Shock melts in QUE 94411, Hammadah al Hamra 237, and Bencubbin: Remains of the missing matrix?

Abstract

We have studied the CB carbonaceous chondrites Queen Alexandra Range (QUE) 94411, Hammadah al Hamra (HH) 237, and Bencubbin with an emphasis on the petrographical and mineralogical effects of the shock processing that these meteorite assemblages have undergone. Ironnickel metal and chondrule silicates are the main components in these meteorites. These hightemperature components are held together by shock melts consisting of droplets of dendritically intergrown Fe,Ni-metal/sulfide embedded in silicate glass, which is substantially more FeO-rich (30 40 wt%) than the chondrule silicates (FeO <5 wt%). Fine-grained matrix material, which is a major component in most other chondrite classes, is extremely scarce in QUE 94411 and HH 237, and has not been observed in Bencubbin. This material occurs as rare, hydrated matrix lumps with major and minor element abundances roughly similar to the ferrous silicate shock melts (and CI). We infer that hydrated, fine-grained material, compositionally similar to these matrix lumps, was originally present between the Fe,Ni-metal grains and chondrules, but was preferentially shock melted. Other shockrelated features in QUE 94411, HH 237, and Bencubbin include an alignment and occasionally strong plastic deformation of metal and chondrule fragments. The existence of chemically zoned and metastable Fe,Ni-metal condensates in direct contact with shock melts indicates that the shock did not substantially increase the average temperature of the rock. Because porphyritic olivine-pyroxene chondrules are absent in QUE 94411, HH 237, and Bencubbin, it is difficult to determine the precise shock stage of these meteorites, but the shock was probably relatively light (S2-S3), consistent with a bulk temperature increase of the assemblages of less than ~300 °C. The apparently similar shock processing of Bencubbin, Weatherford, Gujba (CBa) and QUE 94411/HH 237 (CBb) supports the idea of a common asteroidal parent body for these meteorites.